Monday, July 10, 2017

1.50: Explain How the Structures of Diamond, Graphite and C60 Fullerene Influence their Physical properties, Including Electrical Conductivity and Hardness



GIANT COVALENT STRUCTURE: Contains many Non-Metal atoms joined to adjacent atoms by Covalent Bonds, forming a Giant Lattice Structure
s
DIAMOND

Diagram showing the Structure of Diamond
PROPERTIES:

  1. HARD
s
  • Each Carbon atom is joined to four other Carbon atom to form a Giant Covalent Structure
  • Strong covalent bonds are difficult to break
s
  1. HIGH MELTING POINT (SUBLIMATES)
s
  • Giant Covalent Structure so there are many strong covalent bonds that need to be broken down
  • Large amounts of heat energy is therefore needed to overcome forces and break down bonds
s
  1. DOES NOT CONDUCT ELECTRICITY
s
  • All four valence Electrons are used in covalent bonds so there are no delocalised Electrons that are mobile to conduct electricity

USES:

  1. Cutting Tools

  1. Jewellery





GRAPHITE

Diagram showing the Structure of Graphite
PROPERTIES:

  1. SOFT AND SLIPPERY
s
  • Forces of attraction between layers are weak so layers can easily slide over one another and be separated
s
  1. HIGH MELTING (SUBLIMATES)
s
  • Giant Covalent Structure so there are many strong covalent bonds that needs to be broken down
  • Large Amounts of heat energy is needed to overcome forces and break down bonds
s
  1. CONDUCTS ELECTRICITY
s
  • Only three valence Electrons are used in forming covalent bonds
  • Fourth Electron is delocalised and free to move between layers to conduct an electric charge

USES:

  1. Lubricant

  1. Electrodes for Electrolysis




s
C60 FULLERENE

Diagram showing the Structure of C60 Fullerene
PROPERTIES:

  1. SOFT
s
  • Each Carbon atom is joined to only three other Carbon atoms so has weak intermolecular forces of attraction between molecules
  • Bonds can be broken down easily making it soft
s
  1. LOW MELTING AND BOILING POINT

  • Each Carbon atom is joined to only three other Carbon atoms so has weak intermolecular forces of attraction between molecules
  • Hence, only small amounts of heat energy is needed to overcome forces and break down bonds
s
  1. CONDUCTS ELECTRICITY
s
  • Only three valence Electrons are used in forming covalent bonds
  • Fourth electron is delocalised and free to move to conduct an electric charge

USES:

  1. Drug Delivery System in the Body (Nanotubes)

  1. Lubricant

  1. Catalyst

8 comments:

  1. Diamond sublimates: it doesn't have a boiling point and a melting point.

    ReplyDelete
  2. it says on bbc bitesize that fullerenes have high melting and boiling point due to their giant covalent structure? is this information valid

    ReplyDelete
    Replies
    1. I have just checked BBC bitesize and it says fullerenes do conduct electricity

      Delete
    2. Fullerenes, well at least C60 Fullerene has a low melting and boiling point, does conduct electricity and is not a giant covalent structure.
      Giant covalent structure = truly giant, as in infinite number of atoms involved, however c60 fullerene has a limit, being 60 to 70 atoms and thus is not a giant covalent structure but a simple molecular structure-ish.
      Also know this is a year later but hey the next person might need it

      Delete
  3. Can you ensure me that all the information up to this point is valid, because i have been using this is a revision tool and its working out for me so far up to now. and as the comment above mine says, diamond sublimates? please reply asap

    ReplyDelete
  4. I really thank you for the valuable info on this great subject and look forward to more great posts ECP

    ReplyDelete